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R-Rated hit comedy The Hangover has topped the list of MTV Movie Award nominations, with 6 noms for Best Movie, Best Breakout Star (Zach Galifianakis) Best Comedic Performance (Bradley Cooper and Zach Galifianakis), Best Villain (Ken Jeong) and Best WTF Moment (Ken Jeong - Naked Trunk Surprise.)

Tween hit New Moon and mega-blockbuster Avatar tied for second most nominations with five each.

And even though she may not have had a movie come out this year, Angelina Jolie will be competing against Channing Tatum, Sam Worthington, Chris Pine and Rain in a new category, Biggest Badass.

The 2010 MTV Movie Awards will air live on Sunday, June 6 at 9pm ET.