Jessica Biel  James D'Arcy hitchcock set costume
Jessica Biel  James D'Arcy hitchcock set costume

He plays a villain in the film, but James D'Arcy was all smiles as he chatted up costar Jessica Biel on the set of the upcoming flick, Alfred Hitchcock and the Making of Psycho in Hollywood, on Tuesday afternoon.

The newly engaged star looked retro-chic in a 1960's inspired dress for her role as Vera Miles, who played Janet Leigh's sister in the flick. Scarlett Johansson will reenact Leigh's infamous shower scene, while D'Arcy has been cast as Anthony Perkins, aka the creepy motel owner, Norman Bates.

In other news, Jessica's finace, Justin Timberlake, is gearing up to compose the original soundtrack for her next flick, The Devil and the Deep Blue Sea. We can't wait for the hot couple's summer nuptials!