jessica biel justin timberlake denim westwood trouble with the curve premiere

Jessica Biel and Justin Timberlake know how to make an entrance.

The Hollywood couple arrived at the Trouble with the Curve premiere at the Village Theater in LA dressed to kill.

JT's fiancee rocked a dress by Dolce & Gabbana, a Fendi bag, and Louis Vuitton shoes. So chic!

See all the stars who attended the red carpet event in our gallery below.