Taylor Momsen leggings leather hot dirty soho photoshoot blonde skirt legs boots Black Sheep Syndication

Taylor Momsen was snapped at a shoot in New York City on Tuesday, and the Gossip Girl alum wore an enormous pair of boots, a short leather skirt and a scowl on her face. At first we thought she might have gotten her nose done, but upon closer inspection it looks like it's just some weird contouring makeup on her face.

Despite looking like the world was going to end, Taylor later tweeted, "Great shooting with [Samantha Thavasa] today!!" We're not sure if it's for an ad campaign or a music video (or both?) but AKB48 singer Tomomi Itano was also on hand and Taylor was spotted in a few different outfits with several handbags.

Taylor has been focusing primarily on her band The Pretty Reckless, but we'd love to see her pretty face back on the big or small screen...