It's the divorce shocker of the decade! Angelina Jolie has filed for divorce from Brad Pitt.

The news site has reported that the Hollywood superstar filed for divorce from Brad Pitt last week on Sept. 15, citing irreconcilable differences. And here's the real kicker: she's seeking sole physical custody of the couple's six children.

The site says that the Salt actress, who nabbed divorce-lawyer-to-the-stars Laura Wasser, does NOT want Brad to have joint physical custody, but she will allow him visitation rights and joint legal custody. Yikes! That pretty much means this divorce is not amicable and that Angie does NOT trust Brad to take care of their famous brood.

The outlet is also reporting that the split happened for various reasons but mainly due to parenting styles mixed with a possible substance abuse issue -- and not a third person. A source says that Angelina is "fed up" with Brad's constant weed and possible alcohol consumption, as well as "an anger problem," which she felt endangered her children. Yikes!

It's also possible that the Oscar winner's philanthropic agenda tore them apart? Perhaps Brad no longer handle his lady love's star status? Or did something sketchy happen?

Brad and Angie married in August 2014, but have been together since meeting on the set of Mrs. and Mrs. Smith in 2004.

We don't know exactly what split up the longtime couple ... but there's one thing we do know: JENNIFER ANISTON IS HAVING THE BEST TUESDAY EVER!